PS6 unknown software exception

[bluedragon33]

I put PS6 in my x86 programs folder, but when I clicked on the exe file, it was showing the small VMWare registration splash but then nothing happened. Outside of this folder, or in the 64 bit programs folder, I get an application error: "The exception unknown software exception (0xc06d007f) occurred in the application at location 0x75b92f71." Strangely, after I moved it out of the folder for testing and back in again, I not get the same error no matter where it is. What am I missing?

I'm running on a dual boot BootCamp install of Windows 8 on a MacBook Pro.